• 文献标题:   Facile synthesis of porous graphene-like carbon nitride nanosheets with high surface area and enhanced photocatalytic activity via one-step catalyst-free solution self-polymerization
  • 文献类型:   Article
  • 作  者:   WU SK, WEN SW, XU XM, HUANG GZ, CUI YF, LI JY, QU AL
  • 作者关键词:   porous nanosheet, graphite carbon nitride, selfpolycondensation, photocatalyst
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Jinan Univ
  • 被引频次:   6
  • DOI:   10.1016/j.apsusc.2017.11.254
  • 出版年:   2018

▎ 摘  要

Porous graphite carbon nitride nanosheets (g-C3N4) are achieved via one-step catalyst-free solution self-polymerization from a single melamine precursor. The resultant porous g-C3N4 nanosheets with the best photodegradation capacity provided the surface area of 669.15 m(2)/g, which is superior to the surface area of any other porous g-C3N4 reported. Results showed enhanced adsorption and degradation capacity of methyl orange (MO) under UV-visible light irradiation (lambda > 350 nm) compared to bulk g-C3N4. The MO oxidation of the porous g-C3N4 nanosheets is driven mostly by the participation of holes, and secondly by center dot O-2(-) and center dot OH radicals. This approach shed lights on porous g-C3N4 production simply by self-polycondensation of single functional monomer. It also provided a low-cost and eco-friendly method to facilely mass-produce g-C3N4 nanosheets with high surface area for many potential applications. (C) 2017 Elsevier B.V. All rights reserved.