• 文献标题:   Three-dimensional porous reduced graphene oxide decorated with carbon quantum dots and platinum nanoparticles for highly selective determination of azo dye compound tartrazine
  • 文献类型:   Article
  • 作  者:   MEHMANDOUST M, ERK N, KARAMAN O, KARIMI F, BIJAD M, KARAMAN C
  • 作者关键词:   azo dye, tartrazine, carbon quantum dot, threedimensional graphene oxide, screenprinted carbon electrode, electrochemical sensor
  • 出版物名称:   FOOD CHEMICAL TOXICOLOGY
  • ISSN:   0278-6915 EI 1873-6351
  • 通讯作者地址:  
  • 被引频次:   90
  • DOI:   10.1016/j.fct.2021.112698 EA DEC 2021
  • 出版年:   2021

▎ 摘  要

In this work, an electrochemical sensor for the azo dye compound tartrazine (TRT) determination was proposed. A screen-printed carbon electrode (SPCE) was modified by depositing three-dimensional porous reduced graphene oxide decorated with carbon quantum dots and platinum nanoparticles (Pt/CQDs@rGO/SPCE). The resulting amount of TRT was observed by differential pulse voltammetry. Under optimal conditions, the sensor exhibited two wide linearities ranging from 0.01 to 1.57 mu M and 1.57-9.3 mu M with the reliability coefficient of determination of 0.991 and 0.992, respectively. The detection limit (LOD) was also estimated to be 7.93 nM. Moreover, the Pt/CQDs@rGO/SPCE suggested high selectivity in the presence of several interfering agents and azo dye compounds that have a similar structure. Additionally, the Pt/CQDs@rGO/SPCE revealed superior recovery values of about 96.5-101.6% for candy, 99.7-103.5% for soft drinks, 96.0-101.2% for jelly powder, and 98.0-103.0% for water samples. Furthermore, the fabricated sensor exhibits excellent selectivity, stability, reproducibility, and repeatability, indicating a great perspective in the monitoring of TRT. Therefore, it can be speculated that the proposed electrode could be effectively applied to determine TRT in food samples.