• 文献标题:   Graphene oxide supported Au-Ag alloy nanoparticles with different shapes and their high catalytic activities
  • 文献类型:   Article
  • 作  者:   WU T, MA JK, WANG XR, LIU Y, XU H, GAO JP, WANG W, LIU Y, YAN J
  • 作者关键词:  
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   30
  • DOI:   10.1088/0957-4484/24/12/125301
  • 出版年:   2013

▎ 摘  要

A simple method was developed to fabricate Au-Ag nanoparticle/graphene oxide nanocomposites (Au-Ag/GO) by using simultaneous redox reactions between AgNO3, HAuCl4 and GO. The Au-Ag/GO was characterized by x-ray photoelectron spectroscopy, transmission electron microscopy and energy dispersive x-ray spectroscopy. The GO nanosheets acted as the reducing agent and the support for the Au-Ag alloy nanoparticles. In addition, Au-Ag alloy nanoparticles with different shapes including core-shell-like, dendrimer-like and flower-like were obtained by simply modifying the concentration of the reactants and the reaction temperature. With no reducing or stabilizing agents added, the Au-Ag/GO nanocomposites show superior catalytic performance for the reduction of 4-nitrophenol and for the aerobic homocoupling of phenylboronic acid.