• 文献标题:   Defect- and dopant-controlled carbon nanotubes fabricated by self-assembly of graphene nanoribbons
  • 文献类型:   Article
  • 作  者:   ZHANG C, CHEN SH
  • 作者关键词:   graphene nanoribbon, carbon nanotube, defect, dopant, selfassembly, molecular dynamic
  • 出版物名称:   NANO RESEARCH
  • ISSN:   1998-0124 EI 1998-0000
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   1
  • DOI:   10.1007/s12274-015-0804-0
  • 出版年:   2015

▎ 摘  要

Molecular dynamics simulations showed that a basal carbon nanotube can activate and guide the fabrication of single-walled carbon nanotubes (CNTs) on its internal surface by self-assembly of edge-unpassivated graphene nanoribbons with defects. Furthermore, the distribution of defects on self-assembled CNTs is controllable. The system temperature and defect fraction are two main factors that influence the success of self-assembly. Due to possible joint flaws formed at the boundaries under a relatively high constant temperature, a technique based on increasing the temperature is adopted. Self-assembly is always successful for graphene nanoribbons with relatively small defect fractions, while it will fail in cases with relatively large ones. Similar to the self-assembly of graphene nanoribbons with defects, graphene nanoribbons with different types of dopants can also be self-assembled into carbon nanotubes. The finding provides a possible fabrication technique not only for carbon nanotubes with metallic or semi-conductive properties but also for carbon nanotubes with electromagnetic induction characteristics.