• 文献标题:   Reduced graphene oxide enhanced magnetic nanocomposites for removal of carbamazepine
  • 文献类型:   Article
  • 作  者:   JIANG YJ, CHEN DZ, YANG W, WU SL, LUO XB
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Nanchang Hangkong Univ
  • 被引频次:   0
  • DOI:   10.1007/s10853-018-2712-7
  • 出版年:   2018

▎ 摘  要

Ferrite, as a kind of common magnetic adsorbent, always tend to reuniting and lead to the poor performance for removing contaminant in aqueous. Meanwhile, reduced graphene oxide (rGO), a high-efficiency adsorbent used for water treatment, is hydrophobic and easy to stack because of the Van der Waals force, resulting in the low adsorption capacity. Herein, we prepare the magnetic CoFe2O4/rGO nanocomposites to solve the reuniting of CoFe2O4 and stacking of rGO simultaneously. The rGO nanosheets can improve the dispersion of CoFe2O4 nanoparticles. As sorbent, the adsorption behaviors of carbamazepine on the nanocomposites can be fitted well by the Langmuir and pseudo-secondorder kinetic models. In addition, the CoFe2O4/rGO nanocomposites show enhanced adsorption performance than that of the pure CoFe2O4 nanoparticles, and the loading of rGO can affect their adsorption performance. The adsorption of carbamazepine on CoFe2O4 /rGO is exothermic and mainly controlled by ic-ic interaction and hydrogen bond interaction. Furthermore, the CoFe2O4/rGO can be used to remove other organic pollutants simultaneously. Finally, the nanocomposites can be collected by external magnet, and the regenerated nanocomposites still showed a high adsorption capacity retention (90%) after five cycles.