• 文献标题:   Microwave synthesis of graphene/magnetite composite electrode material for symmetric supercapacitor with superior rate performance
  • 文献类型:   Article
  • 作  者:   KARTHIKEYAN K, KALPANA D, AMARESH S, LEE YS
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Chonnam Natl Univ
  • 被引频次:   82
  • DOI:   10.1039/c2ra21715e
  • 出版年:   2012

▎ 摘  要

Pristine Fe3O4 and Fe3O4-graphene composites were synthesized by using a green and low cost urea-assisted microwave irradiation method and were utilized as electrode materials for symmetric supercapacitor applications. The Fe3O4-graphene symmetric cell exhibited a better electrochemical performance than that of the Fe3O4 cell with enhanced rate performances. The Fe3O4-graphene symmetric cell delivered a stable discharge capacitance, energy and power densities of about 72 F g(-1), 9 Wh kg(-1) and 3000 W kg(-1), respectively at 3.75 A g(-1) current density over 100 000 cycles between 0-1 V. The impedance studies also suggested that the Fe3O4-graphene symmetric cell showed lower resistance and high conductivity due to the small particle size, large surface area and good interaction between Fe3O4 particles and graphene layers.