• 文献标题:   Polyacrylic acid-functionalized graphene oxide for high-performance adsorption of gallium from aqueous solution
  • 文献类型:   Article
  • 作  者:   ZHANG YY, LIU X, WANG YJ, LOU ZN, SHAN WJ, XIONG Y
  • 作者关键词:   adsorption, gallium iii, graphene oxide, polyacrylic acid
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Liaoning Univ
  • 被引频次:   0
  • DOI:   10.1016/j.jcis.2019.08.032
  • 出版年:   2019

▎ 摘  要

Graphene oxide (GO) has great potential in metal recovery and water purification owing to their high surface area, abundant hydroxyl (-OH) and carboxyl (-COOH) groups. To fully understand the influence of the dispersity of GO on the adsorption capacity of metal ions, a series of polyacrylic acid (PAA) function-alized GO (PAA/GO) composites with different dispersity were prepared. The charge density of the PAA/GO composites were much higher than that of the untreated GO in acidic conditions, demonstrating a significant improvement of dispersibility by introducing PAA on the surfaces. Moreover, recovery of gallium by employing the PAA/GO composites as adsorbent were studied. The maximum adsorption capacity towards gallium ions of the adsorbent can reach 196.84 mg.g(-1), much higher than that of other commercially available resins (CL-P204, P507). This superiority could be attributed to the abundant -COOH groups on the surfaces and the good dispersity of the PAA/GO composites. These results revealed that the PAA/GO composites could be promising adsorbents for selective adsorption and efficient recovery of Ga(III). (C) 2019 Elsevier Inc. All rights reserved.