• 文献标题:   Sorption of thorium(IV) from aqueous solutions by graphene oxide
  • 文献类型:   Article
  • 作  者:   LI Y, WANG CL, GUO ZJ, LIU CL, WU WS
  • 作者关键词:   sorption, th iv, graphene oxide, sorption capacity
  • 出版物名称:   JOURNAL OF RADIOANALYTICAL NUCLEAR CHEMISTRY
  • ISSN:   0236-5731 EI 1588-2780
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   16
  • DOI:   10.1007/s10967-014-2956-x
  • 出版年:   2014

▎ 摘  要

Graphene oxide (GO) is one of the most important carbon nano-materials. In this paper, GO was synthesized from flake graphite and characterized by transmission electron microscopy, atomic force microscopy, and X-ray photoelectron spectroscopy. The sorption of Th(IV) on GO was investigated as a function of contact time, solid-to-liquid ratio, pH, ionic strength, and in the presence of fulvic acid (FA) and humic acid (HA) by batch experiments. The sorption percentage of Th(IV) on GO decreased with increasing ionic strength and decreasing solid-to-liquid ratio. The sorption edge of Th(IV) in the presence of FA/HA is much lower than that in the absence of FA/HA. Furthermore, the sorption processes of Th(IV) can be described by a pseudo-second order rate model. Based on the Langmuir model, the maximum sorption capacities (Cs-max) of Th(IV) were about 5.80 x 10(-4) mol/L. From thermodynamic investigation, sorption of Th(IV) on GO is spontaneous and endothermic in nature. The rapid sorption rate and high sorption capacity suggest that GO is a promising adsorbent for Th(IV).