• 文献标题:   Ternary perovskite cobalt titanate/graphene composite material as long-term cyclic anode for lithium-ion battery
  • 文献类型:   Article
  • 作  者:   LI M, XIAO XZ, LIU YJ, ZHANG W, ZHANG YW, CHEN LX
  • 作者关键词:   cotio3, graphene, anode material, electrochemical property
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   13
  • DOI:   10.1016/j.jallcom.2017.01.073
  • 出版年:   2017

▎ 摘  要

A novel perovskite CoTiO3/graphene composite with a particle size of 100 nm was synthesized by ball milling and high temperature solid method and utilized as anode materials for lithium-ion batteries. The structure morphology and electrochemical performance of CoTiO3/graphene nanocomposite were investigated by X-ray diffraction (XRD), Raman spectroscopy measurements, scanning electron microscopy (SEM), galvanostatic charge-discharge tests and electrochemical impedance spectroscopy (EIS) tests. The CoTiO3/graphene nanocomposite delivers a higher stable discharge capacity (similar to 500 mAh g(-1)) and better cycling stability (86.2%), as well as improved rate capability over 80 cycles, compared with those of bare CoTiO3. Moreover, this CoTiO3/graphene nanocomposite exhibits stable discharge capacity (similar to 350 mAh g(-1)) after 3000 cycles at high current density (1 A g(-1)). The improved electrochemical properties of CoTiO3/graphene can be attributed to the good conductivity and large surface of graphene and the combination novel nanostructure of CoTiO3 and graphene. (C) 2017 Elsevier B.V. All rights reserved.