• 文献标题:   0D-2D and 1D-2D Semiconductor Hybrids Composed of All Inorganic Perovskite Nanocrystals and Single-Layer Graphene with Improved Light Harvesting
  • 文献类型:   Article
  • 作  者:   CHEN JS, DOANE TL, LI MX, ZANG HD, MAYE MM, COTLET M
  • 作者关键词:   blinking, electron transfer, perovskite nanocrystals nanowire, singlelayer graphene, singlenanocrystal spectroscopy
  • 出版物名称:   PARTICLE PARTICLE SYSTEMS CHARACTERIZATION
  • ISSN:   0934-0866 EI 1521-4117
  • 通讯作者地址:   Brookhaven Natl Lab
  • 被引频次:   5
  • DOI:   10.1002/ppsc.201700310
  • 出版年:   2018

▎ 摘  要

In this study, inorganic cesium lead iodide (CsPbI3) perovskite nanoparticles (PNPs) and perovskite nanowires (PNWs) with single-layer graphene (SLG) are combined to obtain 0D-2D PNP-SLG and 1D-2D PNW-SLG hybrids with improved light harvesting. Time-resolved single-nanostructure photoluminescence studies of PNPs, PNWs, and related hybrids reveal (i) quasi-two-state photoluminescence blinking in PNPs, (ii) highly polarized photoluminescence emitted by PNWs and (iii) efficient interfacial electron transfer between perovskite nanostructures and SLG in both PNP-SLG and PNW-SLG hybrids. Doping of poorly absorbing, highly conductive SLG with perovskite nanocrystals and nanowires provides a simple, yet efficient path to obtain hybrids with increased light-harvesting properties for potential utilization in the next-generation photodetectors and photovoltaic devices, including polarization sensitive photodetectors.