• 文献标题:   Preparation of graphene/vanadium oxide nanocomposite monolith and its electrochemical performance
  • 文献类型:   Article
  • 作  者:   DENG LJ, MA ZY, LI XB, FAN G
  • 作者关键词:   composite, chemical synthesi, electrochemical propertie, energy storage
  • 出版物名称:   MATERIALS RESEARCH BULLETIN
  • ISSN:   0025-5408 EI 1873-4227
  • 通讯作者地址:   Xianyang Normal Univ
  • 被引频次:   10
  • DOI:   10.1016/j.materresbull.2015.05.034
  • 出版年:   2015

▎ 摘  要

Graphene/vanadium oxide nanocomposite (G/V2O5) monolith is prepared via a simple hydrothermal process. Owing to the intimate contact between the V2O5 nanobelts and graphene nanosheets in the monolith, the nanocomposite shows excellent electric conductivity, and therefore makes the electrod-eelectrolyte contact better and Li+ diffusion faster. A high specific capacitance of 163 F g(-1) has been achieved for G/V2O5 electrode in 0.5 mol L-1 K2SO4 solution. The G/V2O5 nanocomposite exhibits excellent cyclic performance with nearly 80% capacity retention at a current density of 5 A g(-1) in a testing range of 1000 cycles. Moreover, G/V2O5 nanocomposite exhibits excellent discharge properties and cycle stability as an anode material for lithium ion batteries. The initial capacity is 1100 mAh g(-1) and the reversible capacity of 530 mAh g(-1) is maintained after 100 cycles at a current density of 50 mAg(-1). (C) 2015 Elsevier Ltd. All rights reserved.