▎ 摘　　要

Carbon nanotubes/graphene composites are grown on nickel foil without additional catalysts by chemical vapor deposition. Next, to improve the anchoring and uniform dispersing of Co(OH)(2) onto carbon nanotubes/graphene composites, the carbon nanotube/graphene composites are modified by radio frequency nitrogen-plasma. Then porous Co(OH)(2) thin films are galvanostatically electrodeposited onto N-doped carbon nanotubes (CNTs)/graphene composites at different currents and time periods. Finally, the porous Co(OH)(2) is transformed into porous Co3O4 by annealing. The charge specific capacity (1290 mAh g(-1)) reaches a maximum at the galvanostatic electrodeposition condition (current = 1.5 mA and time = 300 s) for the coin cell. Furthermore, Co3PO4/N-doped CNTs/graphene possesses higher charge (discharge) specific capacity and better electrochemical stability in comparison to Co3O4/ CNTs/graphene for the coin cell (full cell: i.e. lithium-ion battery). (C) The Electrochemical Society of Japan, All rights reserved.