• 文献标题:   Graphitic carbon nitride decorated with S,N co-doped graphene quantum dots for enhanced visible-light-driven photocatalysis
  • 文献类型:   Article
  • 作  者:   CAI AJ, WANG Q, CHANG YF, WANG XP
  • 作者关键词:   gc3n4/s n:gqd composite, visible light photodegradation, mechanism
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Hebei Normal Univ Sci Technol
  • 被引频次:   36
  • DOI:   10.1016/j.jallcom.2016.09.030
  • 出版年:   2017

▎ 摘  要

S,N co-doped graphene quantum dots (S, N-GQDs) were successfully combined with graphitic carbon nitride (g-C3N4) in a facile manner by a physical method. The as-prepared g-C3N4/S,N:GQD composites were characterized by X-ray diffraction, high-resolution field-emission scanning electron microscopy, Fourier transform infrared spectroscopy, diffuse-reflectance spectroscopy, photoluminescence spectroscopy, X-ray photoelectron spectroscopy, and other techniques. The g-C3N4/S,N:GQD composites exhibit higher photocatalytic performance for degrading Rhodamine B (RhB) under visible-light irradiation than the pure g-C3N4. The enhancement of photodegradation activity is attributed to the efficient separation of photogenerated electrons and holes. Moreover, these composites can be reused for the degradation of RhB during nine cycles, without a significant decrease in the photocatalytic activity. Finally, a possible charge separation mechanism was proposed. (C) 2016 Elsevier B.V. All rights reserved.