• 文献标题:   Effect of polymer residues on the electrical properties of large-area graphene-hexagonal boron nitride planar heterostructures
  • 文献类型:   Article
  • 作  者:   STEHLE YY, VOYLOV D, VLASSIOUK IV, LASSITER MG, PARK J, SHARMA JK, SOKOLOV AP, POLIZOS G
  • 作者关键词:   graphene, hexagonal boron nitride, heterostructure, interlayer resistance, impedance
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Oak Ridge Natl Lab
  • 被引频次:   3
  • DOI:   10.1088/1361-6528/aa7589
  • 出版年:   2017

▎ 摘  要

Polymer residue plays an important role in the performance of 2D heterostructured materials. Herein, we study the effect of polymer residual impurities on the electrical properties of graphene-boron nitride planar heterostructures. Large-area graphene (Gr) and hexagonal boron nitride (h-BN) monolayers were synthesized using chemical vapor deposition techniques. Atomic van-der-Waals heterostructure layers based on varied configurations of Gr and h-BN layers were assembled. The average interlayer resistance of the heterojunctions over a 1 cm(2) area for several planar heterostructure configurations was assessed by impedance spectroscopy and modeled by equivalent electrical circuits. Conductive AFM measurements showed that the presence of polymer residues on the surface of the Gr and h-BN monolayers resulted in significant resistance deviations over nanoscale regions.