• 文献标题:   Localized Deoxygenation and Direct Patterning of Graphene Oxide Films by Focused Ion Beams
  • 文献类型:   Article
  • 作  者:   LOBO DE, FU J, GENGENBACH T, MAJUMDER M
  • 作者关键词:  
  • 出版物名称:   LANGMUIR
  • ISSN:   0743-7463
  • 通讯作者地址:   Monash Univ
  • 被引频次:   20
  • DOI:   10.1021/la303369m
  • 出版年:   2012

▎ 摘  要

Exposure to controlled doses (similar to 4.65 X 10(-3) to 2.79 x 10(-2) nC/mu m(2) ion fluence) of Ga ions via a focused ion beam (FIB) deoxygenates graphene oxide (GO) and increases the electrical conductivity in 100 x 100 mu m(2) patches by several orders of magnitude compared to that in unexposed GO. Raman spectra and the carbon/oxygen ratio in exposed areas are indicative of chemically reduced graphene oxide (rGO). This novel FIB-induced conversion technique is harnessed for the direct imprinting of complex micrometer-scale shapes and sub-20-nm lines of rGO in insulating films and flakes of GO establishing the capability of generating features varying in size from approximately tens of nanometers to approximately hundreds of micrometers in a maskless, efficient manner.