• 文献标题:   Synthesis, characterization and first application of covalently immobilized nickel-porphyrin on graphene oxide for Suzuki cross-coupling reaction
  • 文献类型:   Article
  • 作  者:   KEYHANIYAN M, SHIRI A, ESHGHI H, KHOJASTEHNEZHAD A
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Ferdowsi Univ Mashhad
  • 被引频次:   4
  • DOI:   10.1039/c8nj04157a
  • 出版年:   2018

▎ 摘  要

In this study, nickel(II)-coordinated 5,10,15,20-tetrakis(aminophenyl)porphyrin (NiTAPP) as a macrocyclic complex was covalently grafted to the edge of graphene oxide (GO). The prepared nanocatalyst was well characterized by various techniques such as FT-IR, Raman, XRD, TEM, SEM, EDX, TGA, ICP-OES, UV and XPS. All analyses confirmed the successful immobilization of NiTAPP on GO. The synthesized catalyst was applied to evaluate its performance in the Suzuki-Miyaura cross-coupling reaction. GO/NiTAPP exhibited good catalytic efficiency with a high yield of products. Moreover, the suggested catalyst could be recycled for five consecutive cycles without a noticeable decrease in its catalytic activity or metal leaching.