• 文献标题:   One-pot electrochemical growth of sponge-like polyaniline-intercalated phosphorous-doped graphene oxide on nickel foam as binder-free electrode material of supercapacitor
  • 文献类型:   Article
  • 作  者:   BIGDELI H, MORADI M, BORHANI S, JAFARI EA, HAJATI S, KIANI MA
  • 作者关键词:   supercapacitor, phosphordoped reduced graphene oxide, polyaniline, electrodeposition
  • 出版物名称:   PHYSICA ELOWDIMENSIONAL SYSTEMS NANOSTRUCTURES
  • ISSN:   1386-9477 EI 1873-1759
  • 通讯作者地址:   MERC
  • 被引频次:   2
  • DOI:   10.1016/j.physe.2018.03.003
  • 出版年:   2018

▎ 摘  要

In this work, phosphor-doped graphene oxide (PGO) was synthesized by chemical technique. Also, the sponge-like PGO@polyaniline nanocomposite (PGO@PANI) film was coated on the nickel foam by one-step electro-polymerization. The active materials were then characterized by Fourier transforms infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy, X-ray diffraction, and Brunauer-Emmett-Teller technique. When PANI/PGO was used as supercapacitor electrode, under current density of 1 A/g, the specific capacitance of the prepared PGO@PANI was measured as 603 F/g, which is 6.0 times higher than that of pure PANI (102 F/g). Moreover, capacity stability of the PANI/PGO increased significantly as compared to PANI (65% vs. 44%) after increasing the current density from 1 to 15 A/g. The clear electrochemical performance of PANI/PGO was enhanced owing to the synergistic effect of PGO and PANI. Our results demonstrate that PANI/PGO nanosheet arrays are promising candidate for electrode supercapacitor applications.