• 文献标题:   Covalently modified graphene quantum dot using a thiourea based imprinted polymer for the selective electrochemical sensing of Hg(II) ions
  • 文献类型:   Article
  • 作  者:   SOMAN S, ASWATHY PV, KALA R
  • 作者关键词:   graphene quantum dot, imprinted polymer technology, voltammetry, mercury sensing
  • 出版物名称:   JOURNAL OF POLYMER RESEARCH
  • ISSN:   1022-9760 EI 1572-8935
  • 通讯作者地址:  
  • 被引频次:   13
  • DOI:   10.1007/s10965-021-02716-6
  • 出版年:   2021

▎ 摘  要

A mercury ion imprinted polymer material was prepared using a thiourea derivative functionalised graphene quantum dot (GQDTU) as the functional monomer using suspension polymerisation technique. This ion imprinted polymer (GQDTU-IIP) material was used to modify the surface of a glassy carbon electrode by drop casting method. The modified electrode was used for the detection of mercury using cyclic voltammetry (CV) and differential pulse voltammetric (DPV) techniques. The sensing performance was compared with a non-imprinted polymer (NIP) modified electrode. The GQDTU-IIP modified electrode showed a linear response towards concentration of Hg(II) ions in the range 5 x 10(-8) M to 2.3 x 10(-5) M using DPV with a limit of detection 23.5 nM. CV also showed linear response ranges of 6 x 10(-8) M to 8.5 x 10(-7) M and 1.4 x 10(-6) M to 7 x 10(-6) M with a limit of detection 30.2 nM. The electrode was used for the analysis of Hg(II) ions in real water samples.