• 文献标题:   Fabrication of high energy Li-ion hybrid capacitor using manganese hexacyanoferrate nanocubes and graphene electrodes
  • 文献类型:   Article
  • 作  者:   PAZHAMALAI P, KRISHNAMOORTHY K, MARIAPPAN VK, KIM SJ
  • 作者关键词:   liion hybrid capacitor, manganese hexacyanoferrate, graphene, aqueous electrolyte, energy density
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   Jeju Natl Univ
  • 被引频次:   5
  • DOI:   10.1016/j.jiec.2018.03.009
  • 出版年:   2018

▎ 摘  要

Herein, we demonstrated a facile sonochemical preparation of manganese hexacyanoferrate (Mn-HCF) and examined its use as an intercalative-type electrode for Li-ion hybrid capacitors (LHCs). The X-ray diffraction, field-emission scanning electron microscopy, and X-ray photoelectron spectroscopic analyses revealed the formation of Mn-HCF nanocubes. The electrochemical analyses revealed the presence of ion-intercalation pseudocapacitance in the Mn-HCF electrode with a specific capacity of 81.59 mAh g(-1). In the view of practical applications, we designed a Mn-HCF parallel to graphene LHC which delivered a high specific capacitance (79.52 F g(-1)) and energy density (44.18 Wh kg(-1)), respectively. Overall, our results highlight the significance of Mn-HCF towards cost-effective energy storage devices. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.