• 文献标题:   The relationship between the structure and electrical properties of a cuprammonium filament via coated graphene
  • 文献类型:   Article
  • 作  者:   ZHANG XC, ZHANG HX, PAN DN, WU W, MA H, CAO JD, XU J
  • 作者关键词:   cuprammonium filament, graphene, layerbylayer assembly, volume resistance, conductive mechanism
  • 出版物名称:   PIGMENT RESIN TECHNOLOGY
  • ISSN:   0369-9420 EI 1758-6941
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1108/PRT-11-2019-0102 EA APR 2022
  • 出版年:   2022

▎ 摘  要

Purpose This paper aims to determine whether application of graphene layers to cuprammonium filaments affords the latter with excellent mechanical properties and improves their electrical properties. At the same time, a circuit model was established to explore the conductive mechanism of the filament. The actual model is used to verify the correctness of the model. Design/methodology/approach The cuprammonium filaments were desizing, the graphene oxide layer-by-layer sizing and reduction integration process by a continuous sizing machine. The electrical properties of mono- and multifilaments in the static condition, as well as the dynamic-mechanical properties of multifilaments, were analysed, and the related conductive mechanism of the filaments was deduced. Findings Cuprammonium filaments coated with graphene layers showed good electrical conductivity, and their volume resistance decreased to 4.35 O center dot cm with increasing number of graphene coats. The X-ray diffraction and thermogravimetric analysis results showed that the graphene layer treatment changed the crystallinity of the copperammonia filaments and improved the thermal stability of the filaments. In the dynamic case, filament resistance was calculated using the equivalent resistance model, and the fitting difference observed was small. This result confirmed the high fit of this circuit model. Originality/value Up to the knowledge from literature review, there are no reports on theoretical research on the relation between the electro-mechanical property and structure of conductive filaments.