• 文献标题:   Silicon doped graphene quantum dots combined with ruthenium(iii) ions as a fluorescent probe for turn-on detection of triclosan
  • 文献类型:   Article
  • 作  者:   DU FY, ZENG QL, LAI Z, CHENG ZF, RUAN GH
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Changsha Univ
  • 被引频次:   3
  • DOI:   10.1039/c9nj03046h
  • 出版年:   2019

▎ 摘  要

Herein, a novel fluorescent probe was developed for the selective and sensitive detection of triclosan (TCS), which is based on turn-on fluorescence of quenched nitrogen silicon doped graphene quantum dot and ruthenium(iii) ion (Si-GQDs/Ru3+) systems. Ru3+ is combined with Si-GQDs which thereby quenches the fluorescence, while the Si-GQDs/Ru3+ complex can be dissociated after the addition of TCS, resulting in fluorescence turn-on. The recovered fluorescence intensity was proportional to the concentration of TCS. The linear range of the probe for TCS detection was 500-25 000 ng L-1, with a low detection limit of 173 ng L-1. This detection platform has been successfully applied for the detection of TCS in both toothpaste and water samples.