• 文献标题:   Electrochemical behavior of polydatin and its highly-sensitive determination based on graphene modified, electrode
  • 文献类型:   Article
  • 作  者:   LI YF, WANG L, ZHAO HP, DU LZ, YE BX
  • 作者关键词:   polydatin, kinetics parameter, electrochemically reduced, graphene oxide
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   1
  • DOI:   10.1016/j.jelechem.2016.04.042
  • 出版年:   2016

▎ 摘  要

A voltammetric sensor for polydatin sensing was simply fabricated by in-situ electrochemically reducing graphene oxide at a glassy carbon electrode. The redox behavior of polydatin was investigated systematically. For the first time, the kinetics parameters of electrode reaction of polydatin were calculated using various electro-chemical techniques. Significant electrochemical signal increases were achieved by the excellent conductivity and large surface area of reduced graphene oxide. Thereafter, a highly-sensitive electroanalytical method for polydatin was established with a good linear relationship from 4.0 x 10(-8) mol L-1 to 3.5 x 10(-8) mol L-1 and a detection limit of 4.0 x 10(-8) mol L-1. In addition, the practical application of present method was demonstrated by determining the concentration of polydatin in real sample with satisfactory result. (C) 2016 Elsevier B.V. All rights reserved.