• 文献标题:   Metal-Graphene Interaction Studied via Atomic Resolution Scanning Transmission Electron Microscopy
  • 文献类型:   Article
  • 作  者:   ZAN R, BANGERT U, RAMASSE Q, NOVOSELOV KS
  • 作者关键词:   graphene, stem, gold, chromium, iron
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Univ Manchester
  • 被引频次:   137
  • DOI:   10.1021/nl103980h
  • 出版年:   2011

▎ 摘  要

Distributions and atomic sites of transition metals and gold on suspended graphene were investigated via high-resolution scanning transmission electron microscopy, especially using atomic resolution high angle dark field imaging. All metals, albeit as singular atoms or atom aggregates, reside in the omni-present hydrocarbon surface contamination; they do not form continuous films, but clusters or nanocrystals. No interaction was found between Au atoms and clean single-layer graphene surfaces, i.e., no Au atoms are retained on such surfaces. Au and also Fe atoms do, however, bond to clean few-layer graphene surfaces, where they assume T and B sites, respectively. Cr atoms were found to interact more strongly with clean monolayer graphene, they are possibly incorporated at graphene lattice imperfections and have been observed to catalyze dissociation of C-C bonds. This behavior might explain the observed high frequency of Cr-cluster nucleation, and the usefulness as wetting layer, for depositing electrical contacts on graphene.