• 文献标题:   Synthesis of Graphene oxide/Porphyrin Nanocomposite for Photocatalytic Degradation of Crystal Violet Dye
  • 文献类型:   Article
  • 作  者:   RAVEENA, SINGH MP, SENGAR M, KUMARI P
  • 作者关键词:   crystal violet dye, graphene, porphyrin, photodegradation, visible light assisted
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/slct.202203272
  • 出版年:   2023

▎ 摘  要

A novel nanocomposite was synthesized by covalent functionalization of graphene oxide (GO) with 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrinatoiron (III) chloride (Fe-THPP) via an ester linkage. The synthesized nanocomposite was characterized by various techniques such as XPS, Raman spectroscopy, BET, IR, UV-Visible, TGA, SEM, and EDX. The synthesized nanocomposite exhibited appreciable interaction with crystal violet (CV) dye with a detection limit of 2.6x10(-6) mu g/mL and binding constant of 35.93x10(3) ppm(-1) which ensured the high concentration of CV dye on the surface of synthesized photocatalyst. The nanocomposite was effectively utilized in the photo-degradation of CV dye under visible light irradiation. The photo-degradation efficiency was remarkably high (93.45 %) with a low catalytic dosage of 0.4 mg/L within 80 minutes. The nanocomposite exhibited good stability and reusability and thereby can be used in the photocatalytic degradation processes to treat wastewater.