• 文献标题:   Flexible Graphene Platform. based Electrochemical Sensor for Sensitive Determination of Dopamine
  • 文献类型:   Article
  • 作  者:   DONG ZJ, ZHANG P, LI SH, LUO HX
  • 作者关键词:   graphene platform electrode, electrochemical sensor, gold nanoparticle, dopamine
  • 出版物名称:   CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
  • ISSN:   0253-3820 EI 1872-2040
  • 通讯作者地址:   Renmin Univ China
  • 被引频次:   0
  • DOI:   10.11895/j.issn.0253.3820.171425
  • 出版年:   2018

▎ 摘  要

The chemical vapor deposition grown graphene was transferred onto flexible polyethylene terephthalate surface to fabricate a graphene platform electrode (GPE), and gold nanoparticles (AuNPs) were electrodeposited on GPE to form an AuNPs modified GPE (AuNPs/GPE). The formation of AuNPs was confirmed by scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), high-resolution transmission electron microscope (HR-TEM), X-ray diffraction (XRD) and Raman spectra. On AuNPs/ GPE, dopamine (DA) displayed a pair of well-defined redox peaks with highly enhanced peak currents compared with those on GPE. At detection potential of 0.20 V, AuNPs/GPE sensor presented a wide linear range of 0.1 timol/L to 400.0 timol/L of DA with a detection limit of 3.9 nmol/L (S/N= 3). In addition, the proposed sensor allowed highly selective and sensitive, stable and fast amperometric sensing of DA.