• 文献标题:   Highly Efficient Fuel Cell Electrodes from Few-Layer Graphene Sheets and Electrochemically Deposited Palladium Nanoparticles
  • 文献类型:   Article
  • 作  者:   HOLTIG M, RUHMLIEB C, KIPP T, MEWS A
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Univ Hamburg
  • 被引频次:   7
  • DOI:   10.1021/acs.jpcc.5b12495
  • 出版年:   2016

▎ 摘  要

An extremely efficient ethanol fuel cell electrode is produced by combining the large surface area of vertically oriented and highly conductive few-layer graphene sheets with electrochemically deposited palladium nanoparticles. The electrodes show an extraordinary high catalyst activity of up to 7977 mA/(mg Pd) at low catalyst loadings of 0.64 mu g/cm(2) and a very high current density of up to 106 mA/cm(2) at high catalyst loadings of 83 mu g/cm(2). Moreover, the low onset potentials combined with a good poisoning resistance and long-term stability make these electrodes highly suitable for real applications. These features are achieved by using a newly developed electrochemical catalyst deposition process exploiting high voltages of up to 3.5 kV. This technique allows controlling the catalyst amount ranging from a homogeneous widespread distribution of small (