• 文献标题:   Visible light induced efficient photocatalytic degradation of azo dye into nontoxic byproducts by CdSe quantum dot conjugated nano graphene oxide
  • 文献类型:   Article
  • 作  者:   DAS S, SOMU P, PAUL S
  • 作者关键词:   quantum dot, cadmium selenide, nano graphene oxide, congo red, photocatalysi, dye degradation
  • 出版物名称:   JOURNAL OF MOLECULAR LIQUIDS
  • ISSN:   0167-7322 EI 1873-3166
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1016/j.molliq.2021.117055 EA AUG 2021
  • 出版年:   2021

▎ 摘  要

We investigated the degradation of an azo dye, Congo red (CR), under the sunlight by using the nanoconjugate of graphene oxide (nGO) and CdSe quantum dots (QD) as the nano-photocatalyst. TEM confirmed the presence of CdSe QD of 4 nm size on the surface of nGO. Our results revealed that with an optimized concentration of 0.5 g/L the synthesized catalyst was most efficient at pH 7.0 with a degradation efficiency of more than 90% for 20 ppm and 100 ppm dye within 60 min of time. The nanoconjugate, having ratio between nGO and CdSe QD (w/w) as 1:5, demonstrated highest degradation efficiency. Further, FTIR spectra of photocatalyst before and after its application confirmed the complete photodegradation of CR. Microbial time kill assay also confirmed the non-toxicity character of photo-degraded by-products. Moreover, the regeneration experiment on nanoconjugate for five cycles of photocatalysis confirmed its high reusability. Thus, our nanoconjugate can be used as effective nano material for the rapid degradation of CR dye under sunlight. (c) 2021 Published by Elsevier B.V.