• 文献标题:   A Practical Li-Ion Full Cell with a High-Capacity Cathode and Electrochemically Exfoliated Graphene Anode: Superior Electrochemical and Low-Temperature Performance
  • 文献类型:   Article
  • 作  者:   SUN ZH, LI Z, WU XL, ZOU MQ, WANG DD, GU ZY, XU JN, FAN YY, GAN SY, HAN DX, NIU L
  • 作者关键词:   electrochemically exfoliated graphene, anode, 3mu m nickelrich oxide, cathode, lowtemperature performance, lithiumion full cell
  • 出版物名称:   ACS APPLIED ENERGY MATERIALS
  • ISSN:   2574-0962
  • 通讯作者地址:   Guangzhou Univ
  • 被引频次:   7
  • DOI:   10.1021/acsaem.8b01524
  • 出版年:   2019

▎ 摘  要

Lithium-ion batteries (LIBs) are widely adopted power sources for portable digital products and electrical vehicles (EV). However, the high cost associated with raw materials and manufacturing and low-temperature performance are primary concerns for largescale deployment of LIBs, especially for EV and grid-scale storage applications. Herein, a novel lithium-ion full cell assembled by 3 mu m-LiNi0.6Co0.2Mn0.2O2 (LNCM-3) cathode and electrochemically exfoliated graphene (EG) anode was fabricated, generating an energy density of similar to 278 Wh kg(-1), which is calculated on the basis of the design of commercial 18650 LIBs. Besides, it also exhibits outstanding rate capability, superior low-temperature electrochemical performance and ultralong cycle life (no capacity fading within 300 cycles at temperatures from 25 to -30 degrees C at 180 mA g(-1)). The proposed novel full cell configuration will enable the next-generation high performance batteries for EV applications.