• 文献标题:   Graphene nanoribbons formed from n-alkane by thermal dehydrogenation on Au(111) surface
  • 文献类型:   Article
  • 作  者:   ENDO O, NAKAMURA M, AMEMIYA K, OZAKI H
  • 作者关键词:   xray absorption spectroscopy, xray photoelectron spectroscopy, scanning tunneling microscopy, nalkane, au 111, dehydrogenation
  • 出版物名称:   SURFACE SCIENCE
  • ISSN:   0039-6028 EI 1879-2758
  • 通讯作者地址:   Tokyo Univ Agr Technol
  • 被引频次:   6
  • DOI:   10.1016/j.susc.2014.12.005
  • 出版年:   2015

▎ 摘  要

A graphene nanoribbon is formed by the dehydrogenation reaction of n-alkane adsorbed on a Au(111) surface. The X-ray absorption spectra at the near carbon K-edge show the appearance of the out-of-plane 1s --> pi* resonance upon heating the n-C44H90 monolayer with the simultaneous disappearance of the 1s --> sigma*(CH)/R (R: Rydberg state) resonance. The pi* resonance located at 284.6 eV reflects a high edge density and is consistent with the ribbon shape, which was observed by scanning tunneling microscopy, and the C 1s XPS peak at 284.0 eV. (C) 2014 Elsevier B.V. All rights reserved.