• 文献标题:   Copper(II) Schiff base complex immobilized on graphene nanosheets: a heterogeneous catalyst for epoxidation of olefins
  • 文献类型:   Article
  • 作  者:   ZARNEGARYAN A, PAHLEVANNESHAN Z, MOGHADAM M, TANGESTANINEJAD S, MIRKHANI V, MOHAMMDPOORBALTORK I
  • 作者关键词:   graphene nanosheet, cu ii schiff base, olefin epoxidation, tbhp, heterogeneous catalyst
  • 出版物名称:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • ISSN:   1735-207X EI 1735-2428
  • 通讯作者地址:   Univ Isfahan
  • 被引频次:   4
  • DOI:   10.1007/s13738-018-1552-3
  • 出版年:   2019

▎ 摘  要

The present paper describes the preparation and characterization of Cu(II) Schiff base complex immobilized onto graphene oxide. The structural and morphological characterization of the heterogeneous catalyst was carried out by different techniques such as Fourier transform infrared and diffuse reflectance UV-Vis spectroscopies, X-ray diffraction, thermogravimetric analysis, nitrogen adsorption-desorption, transmission electron microscopy, field emission scanning electron microscopy and inductively coupled plasma atomic emission spectroscopy. The catalytic activity of the heterogeneous catalyst was studied in the epoxidation of various alkenes using tert-butyl hydroperoxide as an oxidant and it showed high selectivity and catalytic reactivity. The graphene-bound copper Schiff base was successfully reused for several runs without significant loss in its catalytic activity.