• 文献标题:   High Oxidation Resistance of CVD Graphene-Reinforced Copper Matrix Composites
  • 文献类型:   Article
  • 作  者:   WU ML, HOU BS, SHU SC, LI A, GENG Q, LI H, SHI YM, YANG MH, DU SY, WANG JQ, LIAO SZ, JIANG N, DAI D, LIN CT
  • 作者关键词:   cvd graphene, graphene, copper composite, oxidation resistance, electrical contact material
  • 出版物名称:   NANOMATERIALS
  • ISSN:   2079-4991
  • 通讯作者地址:   Hunan Normal Univ
  • 被引频次:   2
  • DOI:   10.3390/nano9040498
  • 出版年:   2019

▎ 摘  要

Copper-based materials are common industrial products which have been broadly applied to the fields of powder metallurgy, electrical contact, and heat exchangers, etc. However, the ease of surface oxidation limits the durability and effectiveness of copper-based components. Here, we have developed a powder metallurgy process to fabricate graphene/copper composites using copper powders which were first deposited with graphene layers by thermal chemical vapor deposition (CVD). The graphene/copper composites embedded with an interconnected graphene network was then able to be obtained by vacuum hot-pressing. After thermal oxidation (up to 220 degrees C) in humid air for several hours, we found that the degree of surface oxidation of our samples was much less than that of their pure Cu counterpart and our samples produced a much smaller increase of interfacial contact resistance when used as electrical contact materials. As a result, our graphene/copper composites showed a significant enhancement of oxidation resistance ability (approximate to 5.6 times) compared to their pure Cu counterpart, thus offering potential applications as novel electrical contact materials.