• 文献标题:   Composites Based on Nanodispersed Nickel, Graphene-Like Carbon, and Aerosil for Catalytic Hydrogenation of Furfural and Quinoline
  • 文献类型:   Article
  • 作  者:   ASAULA VM, SHVETS OV, PARIISKA OO, BUR YANOV VV, RYABUKHIN SV, VOLOCHNYUK DM, KOLOTILOV SV
  • 作者关键词:   composite, nickel, graphenelike carbon, hydrogenation, furfural, quinoline
  • 出版物名称:   THEORETICAL EXPERIMENTAL CHEMISTRY
  • ISSN:   0040-5760 EI 1573-935X
  • 通讯作者地址:   NAS Ukraine
  • 被引频次:   0
  • DOI:   10.1007/s11237-020-09657-z EA OCT 2020
  • 出版年:   2020

▎ 摘  要

It is shown that a composite containing nickel nanoparticles and carboneous multi-layer graphene-like particles on aerosil, prepared by pyrolysis of deposited nickel complex with melamine, catalyzes hydrogenation of furfural to furfuryl alcohol as well as hydrogenation of quinoline to 1,2,3,4-tetrahydroquinoline. The highest yield of hydrogenation products (27% of furfuryl alcohol at 100 degrees C, 30 atm H-2, and 25% of quinoline at 100 degrees C, 100 atm H2) is achieved with the use of composites with higher nickel content (8.4%) and higher size of defect-free graphene areas (ratio of band intensities I-D/I(G)in Raman spectrum 0.9).