• 文献标题:   Reducing Sugar: New Functional Molecules for the Green Synthesis of Graphene Nanosheets
  • 文献类型:   Article
  • 作  者:   ZHU CZ, GUO SJ, FANG YX, DONG SJ
  • 作者关键词:   graphene nanosheet, reducing sugar, electrocatalysi, catecholamine
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   964
  • DOI:   10.1021/nn1002387
  • 出版年:   2010

▎ 摘  要

In this paper, we developed a green and facile approach to the synthesis of chemically converted graphene nanosheets (GNS) based on reducing sugars, such as glucose, fructose and sucrose using exfoliated graphite oxide (GO) as precursor. The obtained GM is characterized with atomic force microscopy, UV-visible absorption spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and so on. The merit of this method is that both the reducing agents themselves and the oxidized Products are environmentally friendly. It should be noted that, besides the mild reduction capability to GO, the oxidized products of reducing sugars could also play an important role as a capping reagent in stabilizing as-prepared GNS simultaneously, which exhibited good stability in water. This approach can open up the new possibility for preparing GNS in large-scale production alternatively. Moreover, it is found that GNS-based materials could be of great value for applications in various fields, such as good electrocatalytic activity toward catecholamines (dopamine, epinephrine, and norepinephrine).