• 文献标题:   Tunable electrochemical properties of fluorinated graphene
  • 文献类型:   Article
  • 作  者:   MEDURI P, CHEN HH, XIAO J, MARTINEZ JJ, CARLSON T, ZHANG JG, DENG ZD
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488
  • 通讯作者地址:   Pacific NW Natl Lab
  • 被引频次:   37
  • DOI:   10.1039/c3ta11710c
  • 出版年:   2013

▎ 摘  要

The structural and electrochemical properties of fluorinated graphene have been investigated by using a series of graphene fluorides (CFx, x = 0.47, 0.66, 0.89). Fluorinated graphene exhibited high capacity retentions of 75-81% of theoretical capacity at moderate rates as cathode materials for primary lithium batteries. Specifically, CF0.47 maintained a capacity of 356 mAh g (1) at a 5 C rate, superior to that of traditional fluorinated graphite. The discharged graphene fluorides also provide an electrochemical tool to probe the chemical bonding on the parent graphene substrate.