• 文献标题:   Preparation of well-dispersed PdAu bimetallic nanoparticles on reduced graphene oxide sheets with excellent electrochemical activity for ethanol oxidation in alkaline media
  • 文献类型:   Article
  • 作  者:   HUANG ZY, ZHOU HH, LI CH, ZENG FY, FU CP, KUANG YF
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   46
  • DOI:   10.1039/c1jm13024b
  • 出版年:   2012

▎ 摘  要

Chemically reduced graphene oxide sheets-supported PdAu (PdAu/CRG) nanocomposites were prepared facilely by co-reduction of graphene oxide sheets, PdCl2 and HAuCl4. Then the PdAu/CRG nanocomposites were characterized by using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The results reveal that PdAu bimetallic nanoparticles with an average diameter of 6 nm are dispersed uniformly on the chemically reduced graphene oxide sheets (CRG). The electrocatalytic performance of the PdAu/CRG catalyst was studied by cyclic voltammetric and chronoamperometric measurements. Electrochemical experiments show that the PdAu/CRG catalyst has excellent catalytic activity and good stability for ethanol oxidation, indicating that the readily available CRG is an outstanding catalyst carrier for ethanol oxidation in alkaline media.