• 文献标题:   Size-Controlled Synthesis of Copper Oxide Particles on Reduced Graphene Oxide for Lithium-Ion Battery Anode Applications
  • 文献类型:   Article
  • 作  者:   JANG H, KIM K, CHANG H, KIM JH, CHOI H
  • 作者关键词:   reduced graphene oxide, copper oxide, solution proces, lithium ion battery
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Kookmin Univ
  • 被引频次:   2
  • DOI:   10.1166/jnn.2015.11576
  • 出版年:   2015

▎ 摘  要

Copper oxide/reduced graphene oxide (rGO) hybrids have been successfully synthesized by attaching copper ions onto the functional groups of GO by means of a solution process, which causes precipitation and agglomeration of copper oxides during subsequent thermal reduction of the GO. The resulting copper oxide/rGO hybrid exhibited improved electrochemical performance compared to monolithic CuO, which is presumed to be due to rGO acting as a mechanical support that buffers the volume change in copper oxides that occurs as a result of the conversion reaction during charge/discharge cycling. Furthermore, it was found that the size of the copper oxide particles can be optimized by adjusting the annealing time, with a hybrid annealed for 30 min achieving a reversible capacity of 544 mA h g(-1) and an initial coulombic efficiency of 62.7%.