• 文献标题:   The mechanism for the stability of graphene oxide membranes in a sodium sulfate solution
  • 文献类型:   Article
  • 作  者:   SUN SA, WANG CY, CHEN MM, LI MW
  • 作者关键词:  
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   24
  • DOI:   10.1016/j.cplett.2013.01.024
  • 出版年:   2013

▎ 摘  要

The stability of graphene oxide (GO) membranes in a sodium sulfate aqueous solution is reported. The mechanism for the stability was interpreted with the assistance of molecular dynamic (MD) simulations as follows: GO disperses uniformly in water because it is hydrated. However, the hydration of GO is weakened when Na2SO4 is present because the Na+ and SO42 ions are preferentially hydrated over GO. Thus the movement of GO in the Na2SO4 solution becomes restricted and it is difficult for the GO in a GO membrane to uniformly disperse in a Na2SO4 solution even with ultrasonic treatment. (C) 2013 Elsevier B.V. All rights reserved.