• 文献标题:   SnS2 quantum dots uniformly anchored on dispersed S-doped graphene as high-rate anodes for sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   JIN SB, SUN XH, CAI S, GUO JZ, FAN AR, ZHANG N, WU H, ZHENG CM
  • 作者关键词:   sns2 quantum dot, sdoped graphene, highrate, sodiumion batterie, capacitive
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   3
  • DOI:   10.1016/j.ceramint.2020.02.237
  • 出版年:   2020

▎ 摘  要

SnS2 stands out to be a potential anode material for sodium-ion batteries (SIBs) owing to its high theoretical capacity and earth abundance. Nevertheless, the severe volume expansion and aggregation of SnS2 would lead to low reversible capacity and poor rate capability. Herein, SnS2 quantum dots uniformly anchored on dispersed S-doped graphene were designed and synthesized via a simple hot bath process with the addition of K+ (K-SnS2@SG). Dispersed S-doped graphene can not only increase the electric conductivity and mitigate the large volume expansion, but also accelerate the electronic/ionic transportation and improve the electrochemically active sites for Na+ storage. Uniformly distributed SnS2 quantum dots can shorten the transfer and diffusion path of Na+/electrons, and the abundant voids around quantum dots can relieve much of volume expansion and keep SnS2 from aggregating. Accordingly, the K-SnS2@SG electrode delivers a high reversible capacity (743 mAh g(-1) at 45 mA g(-1)) and superior rate capability (236 mAh g(-1) at 27 A g(-1)). Furthermore, the kinetic analyses demonstrate that the dominant capacitive behaviors account for excellent rate capability.