• 文献标题:   Two-dimensional sulfur-doped Mn3O4 quantum dots/reduced graphene oxide nanosheets as high-rate anode materials for lithium storage
  • 文献类型:   Article
  • 作  者:   YAO W, QIU WJ, XU ZX, XU JG, LUO JH, WEN YC
  • 作者关键词:   sulfurdoped mn3o4, 2d mesoporous structure, quantum dot, rate capability, lithiumion battery
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Yancheng Inst Technol
  • 被引频次:   3
  • DOI:   10.1016/j.ceramint.2018.08.267
  • 出版年:   2018

▎ 摘  要

Herein, a two-dimensional sulfur-doped Mn3O4 quantum dots/reduced graphene oxide (S-Mn3O4-QDs/rGO) nanosheets are prepared via in-situ sulfidation doping process in a water/ethanol mixed solvent. The 2D nanosheets are made up of ultrafine S-Mn3O4-QDs with a mean diameter of about 5 nm uniformly coated on the surface of rGO. Doping Mn3O4-QDs with sulfur can improve the electrical conductivity of Mn3O4 and increase the specific capacity and rate capability. The strong interaction and synergy effect between S-Mn3O4-QDs and rGO would maintain the integrity of nanosheets and improve the reversibility. As performed as anode materials for lithium-ion batteries, the S-Mn3O4-QDs/rGO anode exhibits a high capacity of 847 mAh g(-1) at a current rate of 0.5 A g(-1) after 100 cycles, and excellent high-rate capability of up to 443 mAh g(-1) at 8 A g(-1), which makes it promising as an anode material for high-performance lithium-ion batteries.