• 文献标题:   Ultrathin CoO/Graphene Hybrid Nanosheets: A Highly Stable Anode Material for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   SUN YM, HU XL, LUO W, HUANG YH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Huazhong Univ Sci Technol
  • 被引频次:   114
  • DOI:   10.1021/jp3070147
  • 出版年:   2012

▎ 摘  要

Transition metal oxides are promising high-capacity anode materials for next-generation lithium-ion batteries. However, their cycle life remains insufficient for commercial applications. Developing transition-metal oxide anode materials with a long lifespan through a facile route has become an important issue. This work reports the fabrication of ultrathin CoO/graphene hybrid nanosheets consisting of ultrafine CoO nanoparticles (similar to 5 nm) densely anchored on the graphene nanosheets. They exhibit a high reversible capacity of similar to 1018.0 mAh g(-1) over 520 discharge/charge cycles, and the Coulombic efficiency remains similar to 100% upon cycling, indicating excellent cyclability. The as-obtained CoO/graphene nanocomposite avoids the widespread problem of cracking or pulverization of transition-metal oxide anode materials upon cycling and retains its original morphology and structure even after 520 discharge/charge cycles, benefiting from the synergetic effects of ultrafine CoO nanoparticles and the conductive graphene nanosheets.