• 文献标题:   Small amount of reduce graphene oxide modified Li4Ti5O12 nanoparticles for ultrafast high-power lithium ion battery
  • 文献类型:   Article
  • 作  者:   CHEN CC, HUANG YA, ZHANG H, WANG XF, LI GY, WANG YJ, JIAO LF, YUAN HT
  • 作者关键词:   lithium titanate, graphene, anode, rate performance, lithium ion battery
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Nankai Univ
  • 被引频次:   63
  • DOI:   10.1016/j.jpowsour.2014.12.075
  • 出版年:   2015

▎ 摘  要

Small amount of reduce graphene oxide (rGO) nanosheets modified Li4Ti5O12 nanoparticles composite has been synthesized by a facile and environmental in-situ hydrothermal reaction with subsequent annealing. The small amount of rGO (only 1.2 wt. %) greatly improves the whole morphology and electrochemical performance of composite. The nanoparticles uniformly grow on the rGO nanosheets effective suppressing the agglomeration and enhancing the specific surface area. Meanwhile, the special discharge capacity is 187 mAh g(-1) at 1 C and the high rates discharge capacity is 128 mAh g(-1) at 80 C (discharge-charge time only 33s). In particular, the cells remain in good work condition after 2000 cycles at 80 C, which credibly evidence the excellent electrochemical performance as an anode for high-power LIBs. (C) 2014 Elsevier B.V. All rights reserved.