• 文献标题:   Fabrication of Polyaniline/Graphene/Tb3+ Conductive Composite Material
  • 文献类型:   Article
  • 作  者:   ZHU XB, XIE TT, MO ZL, ZHAO GP, ZHANG C, GUO RB
  • 作者关键词:   polyaniline, nanocomposite, mechanism, electricity, graphene
  • 出版物名称:   MATERIALS MANUFACTURING PROCESSES
  • ISSN:   1042-6914 EI 1532-2475
  • 通讯作者地址:   Northwest Normal Univ
  • 被引频次:   9
  • DOI:   10.1080/10426914.2014.973581
  • 出版年:   2015

▎ 摘  要

Polyaniline/graphene/Tb3+(PANI/GN/Tb3+) composite material was successfully prepared by the method of in-situ polymerization. The morphology of this as-formed composite material has been confirmed by scanning electron microscope (SEM) analysis. SEM images illustrated that the PANI were uniformly deposited on GN nanosheets. PANI/GN/Tb3+ composite material exhibited high electrical conductivity than the pristine PANI. What's more, results also demonstrated that the synthesized composite material has found wide promising applications in capacitors. Finally, the conductive mechanism of PANI/GN/rare earth composite is discussed in this paper, the conductivity of nanocomposites offered upgrade first than descending latter tendency with different content of Tb3+ ions. The results should be attributed to the special electronic structure and excellent magnetic of rare earth ions, which can influence the polymer chains.