▎ 摘　　要

Advanced materials for electrocatalytic oxygen reduction reaction (ORR) is crucial to a number of renewable energy applications. Herein, a hybrid of nitrogen-doped graphene (N-graphene) and NbOx (x = 2 similar to 2.5) semiconductor nanosheets with sandwich-like structure has been designed and synthesized via a strategy of intercalation-in situ carbonization. The obtained multilayer hybrid material exhibits quite positive onset potential of ORR, good stability and excellent selectivity for ORR with high methanol tolerance. The enhanced performance could be attributed to the active oxygen vacancy from the partial reduction of Nb(V) during the carbonization process and the synergetic coupling effect resulting from the molecular level contact of N-graphene and NbOx (x = 2 similar to 2.5) nanosheets, which makes it a promising substitute of platinum-based materials for renewable energy applications. (C) 2015 Elsevier Ltd. All rights reserved.