• 文献标题:   Glycidyl methacrylate-modified gum arabic mediated graphene exfoliation and its use for enhancing mechanical performance of hydrogel
  • 文献类型:   Article
  • 作  者:   FAN JC, SHI ZX, WANG JL, YIN J
  • 作者关键词:   gum arabic, graphene, hydrogel
  • 出版物名称:   POLYMER
  • ISSN:   0032-3861 EI 1873-2291
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   19
  • DOI:   10.1016/j.polymer.2013.05.057
  • 出版年:   2013

▎ 摘  要

Chemically-modified gum arabic with glycidyl methacrylate was used for liquid-phase direct exfoliation of graphite. Using this technique, glycidyl methacrylate-modified gum arabic-functionalized graphene flakes can be easily obtained by centrifugal separation after sonication. It was demonstrated by transmission electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, Raman spectroscopy and thermogravimetric analysis. The functionalized graphene flakes, coupled with vinyl groups coming from the glycidyl methacrylate-modified gum arabic, were introduced into a poly (acrylic acid) hydrogel to improve its mechanical property. Compared to poly (acrylic acid) hydrogel, the compressive strength and elastic modulus of the graphene/poly (acrylic acid) composite hydrogel with 5 wt% of functionalized graphene flakes reach similar to 49.2 and similar to 66.9 kPa, increased by similar to 846.1% and similar to 243.7%, respectively. (C) 2013 Elsevier Ltd. All rights reserved.