• 文献标题:   Tuning the Electrical Properties of Graphene via Nitrogen Plasma-Assisted Chemical Modification
  • 文献类型:   Article
  • 作  者:   JUNG MW, SONG W, JUNG DS, LEE SS, PARK CY, AN KS
  • 作者关键词:   graphene, n2 plasma treatment, thermal chemical vapor deposition, doping
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Korea Res Inst Chem Technol
  • 被引频次:   1
  • DOI:   10.1166/jnn.2016.11058
  • 出版年:   2016

▎ 摘  要

The control in electrical properties of graphene is essentially required in order to realize graphenebased nanoelectronics. In this study, N-doped graphene was successfully obtained via nitrogen plasma treatment. Graphene was synthesized on copper foil using thermal chemical vapor deposition. After N-2 plasma treatment, the G-band of the graphene was blueshifted and the intensity ratio of 2D-to G-bands decreased with increasing the plasma power. Pyrrolic-N bonding configuration induced by N-2 plasma treatment was studied by X-ray photoelectron spectroscopy. Remarkably, electrical characterization including Hall measurement and I-V characteristics of the N-doped graphene exhibit semiconducting behavior as well as the n-type doping effect.