• 文献标题:   Systematic characterization of transport and thermoelectric properties of a macroscopic graphene fiber
  • 文献类型:   Article
  • 作  者:   MA WG, LIU YJ, YAN S, MIAO TT, SHI SY, YANG MC, ZHANG X, GAO C
  • 作者关键词:   macroscopic graphene fiber, thermoelectric propertie, thermal conductivity, electrical conductivity, seebeck coefficient
  • 出版物名称:   NANO RESEARCH
  • ISSN:   1998-0124 EI 1998-0000
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   18
  • DOI:   10.1007/s12274-016-1231-6
  • 出版年:   2016

▎ 摘  要

Graphene, a two-dimensional material with extraordinary electrical, thermal, and elastic performance, is a potential candidate for future technologies. However, the superior properties of graphene have not yet been realized for graphenederived macroscopic structures such as graphene fibers. In this study, we systematically investigated the temperature (T)-dependent transport and thermoelectric properties of graphene fiber, including the thermal conductivity (lambda), electrical conductivity (sigma), and Seebeck coefficient (S). lambda increases from 45.8 to 149.7 W center dot m(-1)center dot K-1 and then decreases as T increases from 80 to 290 K, indicating the boundary-scattering and three-phonon Umklapp scattering processes. sigma increases with T from 7.1 x 10(4) to 1.18 x 10(5) S center dot m(-1), which can be best explained by the hopping mechanism. S ranges from-3.9 to 0.8 mu V center dot K-1 and undergoes a sign transition at approximately 100 K.