• 文献标题:   High-Throughput Production of Heterogeneous RuO2/Graphene Catalyst in a Hydrodynamic Reactor for Selective Alcohol Oxidation
  • 文献类型:   Article
  • 作  者:   JEONG JM, JIN SB, YOON JH, YEO JG, LEE GY, IRSHAD M, LEE S, SEO D, KWAK BE, CHOI BG, KIM DH, KIM JW
  • 作者关键词:   heterogeneous catalyst, hydrodynamic proces, selective alcohol oxidation, biomassderived hmf, graphene, ruthenium oxide
  • 出版物名称:   CATALYSTS
  • ISSN:  
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   2
  • DOI:   10.3390/catal9010025
  • 出版年:   2019

▎ 摘  要

We report on the high-throughput production of heterogeneous catalysts of RuO2-deposited graphene using a hydrodynamic process for selective alcohol oxidation. The fluid mechanics of a hydrodynamic process based on a Taylor-Couette flow provide a high shear stress field and fast mixing process. The unique fluidic behavior efficiently exfoliates graphite into defect-free graphene sheets dispersed in water solution, in which ionic liquid is used as the stabilizing reagent to prevent the restacking of the graphene sheets. The deposition of RuO2 on a graphene surface is performed using a hydrodynamic process, resulting in the uniform coating of RuO2 nanoparticles. The as synthesized RuO2/IL-graphene catalyst has been applied efficiently for the oxidation of a wide variety of alcohol substrates, including biomass-derived 5-hydroxymethylfurfural (HMF) under environmentally benign conditions. The catalyst is mechanically stable and recyclable, confirming its heterogeneous nature.