• 文献标题:   Nitrogen-doped and simultaneously reduced graphene oxide with superior dispersion as electrocatalysts for oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   LEE CH, YUN JM, LEE S, JO SM, YOO SJ, CHO EA, KHIL MS, JOH HI
  • 作者关键词:   nanostructure, structural material, surface, intercalation reaction, catalytic propertie
  • 出版物名称:   MATERIALS RESEARCH BULLETIN
  • ISSN:   0025-5408 EI 1873-4227
  • 通讯作者地址:   Korea Inst Sci Technol
  • 被引频次:   6
  • DOI:   10.1016/j.materresbull.2014.07.015
  • 出版年:   2014

▎ 摘  要

Nitrogen doped graphene oxide (Nr-GO) with properties suitable for electrocatalysts is easily synthesized using phenylhydrazine as a reductant at relatively low temperature. The reducing agent removes various oxygen functional groups bonded to graphene oxide and simultaneously dope the nitrogen atoms bonded with phenyl group all over the basal planes and edge sites of the graphene. The Nr-GO exhibits remarkable electrocatalytic activities for oxygen reduction reaction compared to the commercial carbon black and graphene oxide due to the electronic modification of the graphene structure. In addition, Nr-GO shows excellent dispersibility in various solvent due to the dopant molecules. (C) 2014 Elsevier Ltd. All rights reserved.