• 文献标题:   Fructose determination in fruit juices using an electrosynthesized molecularly imprinted polymer on reduced graphene oxide modified electrode
  • 文献类型:   Article
  • 作  者:   MOREIRA LFPP, BUFFON E, DE SA AC, STRADIOTTO NR
  • 作者关键词:   fructose, fruit juice, phenylboronic acid, molecularly imprinted polymer, reduced graphene oxide, electrochemical sensor
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:  
  • 被引频次:   17
  • DOI:   10.1016/j.foodchem.2021.129430 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

The present work reports the development of a novel electrochemical sensor for the selective detection of fructose. The sensor was developed through electropolymerization of a molecularly imprinted polymer film on a reduced graphene oxide modified electrode. The modified electrode was characterized by cyclic voltammetry, electrochemical impedance spectroscopy, scanning electron microscopy, atomic force microscopy and RAMAN spectroscopy. Through the application of the modified electrode, the recognition of fructose molecules occurred in a concentration range of 1.0 x 10-14 to 1.0 x 10-11 mol L-1, under a Langmuir adsorption isothermal model. The sensitivity and limits of detection and quantification obtained for the sensor were 9.9 x 107 A L mol-1, 3.2 x 10-15 mol L-1 and 1.1 x 10-14 mol L-1, respectively. The analytical method used for the detection of fructose presented good reproducibility, stability and accuracy, and was successfully applied for the quantification of this sugar in orange, apple and grape juices.