• 文献标题:   Graphene nanomaterials supported palladium nanoparticles as nanocatalysts for electro-oxidation of methanol
  • 文献类型:   Article
  • 作  者:   LI ZP, RUAN M, DU LQ, WEN GM, DONG C, LI HW
  • 作者关键词:   nitrogendoped graphene quantum dots ngqds, palladium nanoparticle, methanol
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Shanxi Univ
  • 被引频次:   8
  • DOI:   10.1016/j.jelechem.2017.10.015
  • 出版年:   2017

▎ 摘  要

We herein report a facile hydrothermal approach to prepare well-dispersed nitrogen-dopedgraphene quantum dots-supported Pd (N-GQDs/Pd) nanocomposites of a narrow size distribution with diameter of 4.8 +/- 0.2 nm. The N-GQDs/Pd nanocomposite demonstrates an excellent electrocatalytic activity for the methanol oxidation reaction in an alkaline medium when compared with the graphene sheets-supported Pd nanocomposites (GS/Pd), graphene quantum dots supported Pd nanocomposites (GQDs/Pd) and commercial palladium catalyst (Pd/C). The N-GQDs/Pd of good dispersion and, small and narrow size distribution offers superior electrical conductivity and remarkable cycling stability. In addition, it offers promising and attractive practical opportunities for electronic materials which possess high catalytic activity and stability, yet the noble metal usage is reduced. This study demonstrated the potential use of N-GQDs/Pd as new electrocatalytic nanomaterials for direct methanol fuel cells.